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B4C-TiB2 ceramics (TiB2 ranging 5~70 vol%) with Mo-Co-WC as the sintering additive were prepared by spark plasma sintering. In comparison with B4C-TiB2 without additive, the enhanced densification was evident in the sintered specimen with Mo-Co-WC additive. Core-rim structured grain was observed around TiB2 grains. The interface of the rim between TiB2 and B4C phases demonstrated different feature: the inner borderline of the rim exhibited a smooth feature, whereas a sharp curved grain boundary was observed between the rim and the B4C grain. The formation mechanism is discussed: the epitaxial growth of (Ti,Mo,W)B2 rim around the TiB2 core may occur as a result of the solid solution and dissolution-precipitation between TiB2 phase and the sintering additive. It was revealed that the fracture toughness increased as the content of TiB2 content increased, alongside the decreased hardness. B4C-30 vol% TiB2 specimen demonstrated the optimal combination of mechanical properties, reaching Vickers hardness of 24.3 GPa and fracture toughness of 3.33 MPa·m1/2.  相似文献   
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《Ceramics International》2022,48(15):21502-21514
Based on the good osteogenic and angiogenic effects of silicon and magnesium elements, three types of micro-nano magnesium-containing silicates (MS), including akermanite (Ake, Ca2MgSi2O7), diopside (Dio, CaMgSi2O6) and forsterite (For, Mg2SiO4), were incorporated into calcium phosphate cement (CPC) to improve its osteogenic and angiogenic performances for clinical application. In this present work, the physicochemical properties, osteogenesis and angiogenesis of MS/CPCs (Ake/CPCs, Dio/CPCs and For/CPCs) were investigated systematically and comparatively. The results showed that all MS/CPCs had good biomineralization and significantly stimulated the osteogenic differentiation of mBMSCs and angiogenic differentiation of HUVECs, respectively. Besides, the stimulating effects were related to not only the category of MS, but also the content of MS. The For/CPCs had a good angiogenic property but their initial setting times were beyond 60 min. The Dio/CPCs showed the lowest biological performance among the three groups of MS/CPCs due to the lower ion release (Si and Mg). The Ake was the ideal modifier that could provide CPC with appropriate physicochemical properties, better osteogenesis and angiogenesis. Simultaneously, a higher addition (10 wt%) of akermanite resulted in the best potential to bone regeneration. Taken together, this research provides an effective approach to improve the overall performance of CPC, and 10Ake/CPC is of great promising prospect in bone repair.  相似文献   
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Unlike fracture toughness, the notch fracture toughness of a ceramic is not a constant; rather, it increases with the notch-root radius ρ in a notched specimen. In this study, by analyzing the fracture measurements of eight different notched ceramics with an average grain size G of 3–40 μm, a simple model describing the relation between the notch fracture toughness and fracture toughness is proposed as a function of the relative notch-root radius ρ/G. The normal distribution is incorporated to consider the inevitable scatter in measurements where fracture mechanisms and errors are present. The results demonstrate that the model can effectively predict the quasi-brittle fracture variation trend for ceramics, including the upper and lower bounds, with 96% reliability, from a normal distribution; thus, it can address virtually all of the experimental data. We also determined that the notch fracture toughness approximates the fracture toughness if ρG.  相似文献   
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This paper discusses the effects of the grinding-induced cyclic heating on the properties of the hardened layer in a plunge cylindrical grinding process on the high strength steel EN26. It was found that a multi-pass grinding brings about a uniform and continuous hardened layer along the circumference of the cylindrical workpiece. An increase of the number of grinding passes, leads to a thicker layer of hardening, a larger compressive residual stress and a deeper plastic deformation zone. Within the plastic deformation zone, the martensitic grains are refined by the thermo-mechanical loading, giving rise to a hardness of 12.5% higher than that from a conventional martensitic transformation. The coupled effects of heat accumulation and wheel wear in the multi-pass grinding are the main causes for the thickening of the hardened layer. A too small infeed per workpiece revolution would result in insufficient grinding heat, and in turn, bring about an undesirable tempered hardened layer and a reduction of its hardness.  相似文献   
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ZrB2-SiC coatings with different ZrB2 contents were prepared by liquid phase sintering. The oxidation processes of coatings were explained according to TG results of ZrB2-SiC coatings and powders tested from 298 K to 1773 K. Results show that, increasing ZrB2 content made the weight of the samples changed from weight-loss of 10.04% to weight-gain of 0.14%, while the fastest weight-loss regions were narrowed, whose inflection points reduced from 1310℃ to 1050℃. Increasing ZrB2 content made the relative oxygen permeability of the ZrB2-SiC/SiC coatings reduced from 40%–60% to -10%-5%. Increasing ZrB2 content enhanced high-temperature stability of coatings, making final weight of samples changed from weight-loss of 0.16% to weight-gain of 0.11% after oxidation at 1773 K for 200 h. The peeling and dispersion of Zr-oxides formed Zr-B-Si-O compound glass layer, presenting enhanced stability, dispersion strengthening and pinning effect of Zr-oxides, which were responsible for the excellent anti-oxidation protective effect of coatings in a broad temperature region.  相似文献   
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李勘  孙树栋 《鱼雷技术》2008,16(5):8-11
将层次分析法(AHP)与数据包络法(DEA)有机结合,构建了AHP—DEA的鱼雷方案评价模型,首先通过AHP法计算各鱼雷方案在评价因素中的相对权重,然后根据DEA法的原理将鱼雷方案作为决策单元、各方案的相对权重作为产出建立优化模型,通过计算模型的相对效率值,求出鱼雷方案可能性大小的顺序,并以实例阐述该模型在鱼雷方案评价中的具体运用。  相似文献   
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连铸二次冷却智能优化控制的研究   总被引:1,自引:0,他引:1  
陈志凌  张国贤  韩传基 《钢铁》2006,41(9):40-43
针对连铸二冷目标温度控制法存在的系统不稳定、水量计算波动大等问题,以连铸二冷温度场数值计算为基础,采用在冶金约束条件允许下的变化目标温度,变化初始水量的方法,解决二冷动态控制实施过程中存在的问题.运用神经网络对函数的逼近能力与自学习能力构造目标温度控制模型(TTANN)、二冷水控制模型(IWANN)、设计智能PID控制器,与连铸坯温度计算模型组成连铸二冷控制系统,实现连铸二冷动态优化控制.仿真结果表明,温度动态控制精度小于12℃.  相似文献   
10.
为科学决策和评价驾驶人情绪感知装置的最优化多模态组合方案, 本文基于可拓设计多功能产品创造法, 利用基元理论中的发散分析法分析了情绪感知装置的检测功能, 建立了类物元,并生成具体产品物元模型。分析了单一检测装置包含的3种安装位置间的重组关系, 拓展出一系列重组方案, 再利用优度评价法对其进行筛选。 最终确定了一种有效的多模态驾驶人情绪感知装置的组合方案。  相似文献   
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